Kazakhstan journal for oil & gas industryKazakhstan journal for oil & gas industry2707-42262957-806XKMG Engineering10865310.54859/kjogi108653Review ArticleProspects for the use of energy-accumulating substances in solving environmental problems in the oil industryBoikoGalina I.<p>D. Sc. (Chemistry), professor</p>g.boiko@satbayev.universityhttps://orcid.org/0000-0003-2719-7045SarmurzinaRaushan G.<p>D. Sc. (Chemistry), professor</p>sarmurzina_r@mail.ruhttps://orcid.org/0000-0002-9572-9712GalievaNina P.<p>Cand. Sc. (Chemistry)</p>amtek@bk.ruhttps://orcid.org/0000-0002-7133-808XKarabalinUzakbay S.<p>D.Sc. (Engineering), professor</p>reception@kazenergy.comhttps://orcid.org/0000-0002-7471-7851TiessovDaniyar S.cv@kpi.kzAkhanovaTanzilya R.tanzilyaziyayeva@gmail.comhttps://orcid.org/0000-0002-8343-1150KenyaikinPavel V.kenyaikin.p@gmail.comhttps://orcid.org/0000-0002-4360-1573Satbayev UniversityKAZENERGYKazakhstan Petrochemical Industries Inc.1807202352991162405202321062023Copyright © 2023, Boiko G.I., Sarmurzina R.G., Galieva N.P., Karabalin U.S., Tiessov D.S., Akhanova T.R., Kenyaikin P.V.2023<p>The prospects for using new-generation energy-accumulating substances based on aluminum alloys activated with activating metals (indium, gallium, tin, eutectics of low-melting metals) as non-traditional environmentally friendly sources for hydrogen production from water and energy accumulation methods, the formation of various forms of aluminum hydroxides, are discussed, which can be used in solving environmental problems in the oil industry: in technologies for complex oil treatment, destruction of abnormally stable water-oil emulsions and oil sludge, demetallization and desulphurization of hydrocarbon raw materials, for the treatment of industrial waste, recycled and natural waters, as well as the reclamation of oil-contaminated areas with low and average levels of pollution, restoration of their fertility when used together with organomineral (humic) fertilizers.</p>aluminumactivationoil sludgealloysenergy-accumulating substancesалюминийактивациямұнай шламдарықорытпаларэнергия шоғырландырушы заттаралюминийактивациянефтешламысплавыэнергоаккумулирующие вещества1.Trowell KA, Goroshin S, Frost DL, Bergthorson JM. Aluminum and its role as a recyclable, sustainable carrier of renewable energy. Applied Energy. 2020;275. doi:10.1016/j.apenergy.2020.115112.2.Najafpour MM, Mehrabani S, Bagheri R, et al. An aluminum/cobalt/iron/nickel alloy as aprecatalyst for water oxidation. International Journal of Hydrogen Energy. 2018;43(4): 2083–2090. doi:10.1016/j.ijhydene.2017.12.025.3.Pini M, Breglia G, Venturelli M, et al. Life cycle assessment of an innovative cogeneration system based on the aluminum combustion with water. Renewable Energy. 2020;154. doi:10.1016/j.renene.2020.03.046.4.Egilegor B, Jouhara H, Zuazua J, et al. ETEKINA: analysis of the potential for waste heat recovery in three sectors: aluminium low pressure die casting, steel sector and ceramic tiles manufacturing sector. Int. J. Thermofluids. 2020;1–2. doi:10.1016/j.ijft.2019.100002.5.Blanco H. What will an international marketplace for Hydrogen look like? Energypost. Cited 2023 May 5. Available from: https://energypost.eu/what-will-an-international-marketplace-for-hydrogen-look-like.6.Mazloomi K, Gomes C. Hydrogen as an energy carrier: prospects and challenges. Renew. Sustain. Energy Rev. 2012;16:3024–3033. doi:10.1016/j.rser.2012.02.028.7.Author's certificate № 535364/ 15.11.76. Byul. 42. Sokolsky DV, Kozin LF, Barmin VP, Podgorny AN, Varshavsky NA, Sarmurzina RG, Ospanov E. Aluminum-based alloy for production of hydrogen.8.Zhang F, Yonemoto R, Arita M, Horita Z. Hydrogen generation from pure water using Al-Sn powders consolidated through high-pressure torsion. J Mater Res. 2016;31(7):75–82. doi:10.1557/jmr.2016.74.9.Dlya MI, Balyabina AA, Drozdova NV. Hydrogen energy and prospects of its development. Alternative Energy and Ecology (ISJAEE). 2015;22:37–41. doi:10.15518/isjaee.2015.22.004. (In Russ).10.Bersh AV, Kleymenov BV, Mazalov YA, Nizovtsev VE. Prospects of development of hydrogen energy based on aluminum. Radioelectronics and Telecommunications. 2005. 2(38):62–66. (In Russ).11.Ilyukhina AV, Kravchenko OV, Bulychev BM, Shkolnikov EI. Mechanochemical activation of aluminum with gallams for hydrogen evolution from water. International journal of hydrogen energy. 2010;35:1905–1910. doi:10.1016/j.ijhydene.2009.12.11.12.Sheidlin AE, Zhuk AZ. Alumina-Hydrogen Energy. Bulletin of the Russian Academy of Sciences. 2010;80(3):218–224. (In Russ).13.Ilyukhina AV, Kravchenko OV, Bulychev BM. Studies on microstructure of activated aluminum and its hydrogen generation properties in aluminum/water reaction. Journal of Alloys and Compounds. 2017;690:321–329. doi:10.1016/j.jallcom.2016.08.151.14.Huang T, Gao Q, Liu D, et al. Preparation of Al-Ga-In-Sn-Bi quinary alloy and its hydrogen production via water splitting. International Journal of Hydrogen Energy. 2015;40(5):2354–2362. doi:10.1016/j.ijhydene.2014.12.034.15.Ziebarth JT, Woodall JM, Kramer RA, Choi G. Liquid phase-enabled reaction of Al-Ga and Al-Ga-In-Sn alloys with water. Int. J. Hydrogen Energy. 2011;36(9):5271–5279. doi:10.1016/j.ijhydene.2011.01.127.16.Patent RK № 34988/ 09.04.21. Byul. № 14. Sarmurzina RG, Boiko GI, Karabalin US, Tiyesov DS, Lyubchenko NP, Baigazyev MT, Boiko EA. Alloy for hydrogen production and method of its preparation. (In Russ).17.Patent RK № 34806/ 22.07.19. Byul. № 3. Sarmurzina RG, Boiko GI, Karabalin US, Tiyesov DS, Lyubchenko NP, Baigaziyev MT, Boiko EA, Mamutov ME. Alloy for hydrogen production on the basis of aluminum and method of its preparation.18.Patent RK № 34807/ 22.01.21. Byul. № 3. Sarmurzina RG, Boiko GI, Karabalin US, Lyubchenko NP, Tiyesov DS, Baigaziyev MT, Mamutov ME. Alloy for hydrogen production on the basis of aluminum and the method of its preparation.19.Sarmurzina RG, Karabalin US, Tiessov DS, Lyubchenko NP, Baygaziev MT. Prospects of using hydrogen energy in technologies of complex oil treatment, destruction of abnormally stable water-oil emulsions and oil sludge. Oil.Gas.Novations. 2019;5(222):26–31. (In Russ).20.Patent RK № 311164/ 16.05.16. Byul. № 5. Sarmurzina RG, Karabalin US, Dosmukhambetov MD, Iskaziev K, Boiko GI, Moldabekov BS, Lyubchenko NP. Method of treatment of bottomhole formation zone. (In Russ).21.Baigaziev MT, Sarsenbekov ND, Boiko GI, et al. Study of impact of activated aluminum alloy on cores saturated with oil fields of Kazakhstan. Petroleum industry. 2018;7:68–89. doi:10.24887/0028-2448-2018-7-86-89. , (In Russ).22.Eurasian Patent № 033942B1/ 12.12.19. Byul. № 7. Sarmurzina RG, Boiko GI, Lyubchenko NP, Baigaziyev MT, Karabalin US, Akchulakov BU, Kozyrev DV. Method of oil sludge destruction.23.Patent RK № 33660/ 07.06.19. Byul. № 23. Sarmurzina RG, Boiko GI, Lyubchenko NP, Baigaziev MT, Karabalin US, Akchulakov BU, Kozyrev DV. Method of oil sludge destruction.24.Patent RK № 33863/ 06.07.19. Byul. Sarmurzina RG, Boiko GI, Lyubchenko NP, Nabidollayev SE, Karabalin US, Akchulakov BU, Kozyrev DV, Boiko EA. Method of extraction of non-ferrous metals from heavy oil raw materials.25.Patent RK № 34095/ 30.03.20. Byul. № 11. Boiko GI, Sarmurzina RG, Karabalin US, Tiessov DS, Lyubchenko NP, Nabidollaev SE.,Boiko EA. Method of removing sulfur from oil raw materials.26.Yang B, Zhu J, Jiang ., et al. Effect of heat treatment on Al-Mg-Ga-In-Sn alloy reaction for hydrogen generation through hydrolysis. International Journal of Hydrogen Energy. 2017;42(38):24393–24403. doi:10.1016/j.ijhydene.2017.07.091.27.Kuznetsova VV, Loik AV. Energy storage substances as an alternative fuel for stationary and transport power plants. Proceedings of the Moscow State Machine-Building University "MAMI". 2014;4(22):41–46. (In Russ).28.Boiko GI, Sarmurzina RG, Lyubchenko NP, et al. Prospects of using active aluminium in hydrogen power engineering and oil and gas complex. Proceedings of the World Congress of Engineers and Scientists "Energy of the Future: Innovative Scenarios and Methods of their Implementation” WSEC. 2017;3:125–130. (In Russ).29.Sarmurzina RG, Boiko GI, Baigaziyev M, et al. New generation of energy accumulating substances on the basis of activated aluminum. Journal of chemical technology and metallurgy. 2018;53(1):119–124.30.Sarmurzina RG, Boiko GI, Lyubchenko NP, et al. Аlloys for the production of hydrogen and active aluminum oxid. National Academy of Sciences of the Republic of Kazakhstan. Series of geology and technical sciences 1. 2022;1(451):91–98. doi:10.32014/2022.2518-170X.145.31.Sarmurzina RG, Boiko GI, Lyubchenko NP, et al. Hydrogen obtaining from the system activated aluminum water. National Academy of Sciences of the Republic of Kazakhstan. Series of geology and technical sciences 6. 2022;6(456):196–213. doi:10.32014/2518-170X.249.32.Lee CH, Tiwari B, Zhanga D, et al. Water purification: oil–water separation by nanotechnology and environmental concerns. Environ. Sci.: Nano. 2017;4:514–525. doi:10.1039/c6en00505e.33.Boiko GI, Ziyaeva TR, Mukhamedova RF, et al. Humic acids and their polymeric forms as natural detoxicants of soil from oil pollution. Theory and practice of chemical technology (Marushkin readings-VI). 2021;2:328–329. (In Russ).34.Sarmurzina RG, Boiko GI, Kenzhaliyev BK, et al. Coagulants for water based on activated aluminum alloys. Global J. Environ. Sci. Manage. 2023;9(4):673–690. doi:10.22034/gjesm.2023.04.2.35.Patent RK № 35912/ 21.10.22. Boiko GI, Sarmurzina RG, Galieva NP, Kenyaikin PV, Karabalin US, Tiessov DS, Boiko EA. Method of treatment of oily wastewater.36.Patent RK № 35913/21.10.22. Boiko GI, Sarmurzina RG, Galieva NP, Kenyaikin PV, Karabalin US, Tiessov DS. Method of treatment of oily wastewater.37.Patent RK № 36031/30.12.22. Boiko GI, Sarmurzina RG, Galieva NP, Kenyaikin PV, Karabalin US, Tiessov DS, Boiko LS. Method of treatment of oily wastewater.